Functionalised N–Heterocyclic Carbene Complexes
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Описание:
N–heterocyclic carbenes (NHCs) have found increasing use as reagents for a range of organic transformations and in asymmetric organocatalysis. The performance of these molecules can be improved and tuned by functionalisation. Functionalised carbenes can anchor free carbenes to the metal site, introduce hemilability, provide a means to immobilise transition metal carbene catalysts, introduce chirality, provide a chelate ligand or bridge two metal centres. NHCs can be attached to carbohydrates and campher, derived from amino acids and purines, and they can be used as organocatalysts mimicking vitamin B1 or as weak “solvent” donors in lanthanide chemistry. Functionalised N–Heterocyclic Carbene Complexes describes major trends in functionalised NHC ligands, aiming to assist readers in their attempts to develop and apply their own functionalised carbenes. After an introduction to the chemistry and behaviour of NHC, the book gives a detailed description of functionalised...Похожие книги
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