Ultrafast Vibrational Dynamics of Diatomic Halogens in Ices

Ultrafast Vibrational Dynamics of Diatomic Halogens in Ices
Автор
 
Год
 
Страниц
 
220
ISBN
 
9783639101621
Категория
 
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Описание:

Understanding dynamics in condensed media is a subject of contemporary interest in chemistry and physics. Our studies have been focused on photo-induced vibrational and electronic dynamics of halogens in ices and clathrate hydrates. The goal of our research is understanding the dynamics of halogens and solvent, the effect of the solvent on dynamical observables - issues of fundamental importance to chemistry. The focus of my research and hence the subject of the thesis concerns the photodynamical studies of molecular bromine and iodine (the guest) isolated in ice (the host), as part of a bigger aim in investigating photodynamics in clathrate hydrates. Our studies of photo-induced vibrational and electronic dynamics of molecular halogens in these complex media aim at addressing the following issues, which are of fundamental importance to physical chemistry: How do the ice or clathrate hydrate environments affect the dynamics of the trapped halogens? Can the guest chromophore be used as...

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